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Sublimation

Sublimation is a process that transfers designs onto fabric using heat to essentially embed the ink into the fabric, and bring the ink and fabric together as one. It is very useful for printing onto whole garments seam-to-seam to create an "all over print". Only 100% polyester materials can be sublimated- any other fabric will not absorb the ink as well and will not look good. 

Here you can read up on more information about sublimation printing and how it works.